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Creators/Authors contains: "Riffel, Madeline N."

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  1. ; ; ; (, Chemical Science)
    Redox-inert metal cations change the reaction between thiolate anions and elemental sulfur. Spectroscopic and electrochemical data show that metal–sulfur covalency determines the favorability of sulfur catenation vs. sulfur reduction. 
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  2. ; ; ; (, Dalton Transactions)
    Zn II and Fe II chloride complexes of a di(methylthiazolidinyl)pyridine ligand were deprotonated to form the corresponding thiolate complexes supported by redox-active iminopyridine moieties. The thiolate donor groups are nucleophilic and reactive toward oxidants, electrophiles, and protons, while the pendant thiazolidine rings are available for hydrogen bonding. Anion exchange with the weakly-coordinating triflate anion resulted in self-assembly of the iminopyridine complexes to form a trimeric [M 3 S 3 ] cluster. Hydrogen bonding closely associates anions with this trimetallic core. 
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